Abstract: Interpersonal behavior between college students not only improves students' capabilities, but also affects the harmonious development of inter-college network. The information age extends relationships from blood, geography and industry to internet with three main kinds of interactions, they are peer-to-peer, peer-to-group and group-to-group. College students' interpersonal network is mainly composed of individual and instrumental value. While, in practice, both the subject and object of such interpersonal behavior are alienated because of factors from their subjects, technology and external. Our work discussed the adjustment of college students' interpersonal behavior from three aspects: deepening ideological and political education and finding the best network of good governance, heteronomy; building students' network moral subject, autonomy; creating specification and freedom uniting heteronomy, autonomy and etc.