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DANG Lizhi, ZHANG Yipeng, ZHANG Jian, et al. Fast Recognized the Flavoniod Glycosides from Rosmarinus Officinalis Linn by LC-MS Technique[J]. JOURNAL OF YUNNAN AGRICULTURAL UNIVERSITY（Natural Science）, 2017, 32(2): 358-365. DOI: 10.16211/j.issn.1004-390X(n).2017.02.023
Citation: DANG Lizhi, ZHANG Yipeng, ZHANG Jian, et al. Fast Recognized the Flavoniod Glycosides from Rosmarinus Officinalis Linn by LC-MS Technique[J]. JOURNAL OF YUNNAN AGRICULTURAL UNIVERSITY（Natural Science）, 2017, 32(2): 358-365. DOI: 10.16211/j.issn.1004-390X(n).2017.02.023
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Fast Recognized the Flavoniod Glycosides from Rosmarinus Officinalis Linn by LC-MS Technique

  • Yunnan Tobacco Industrial Co., Ltd., Kunming 650231, China

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  • Received Date: January 10, 2016
  • Revised Date: April 26, 2016
  • Published Date: March 29, 2017
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    • Abstract
  • To determine the chemical component of Rosmarinus officinalis and study the fragmentation rules of the main constituent, the crude extract of R.officinalis Linn was analyzed by LC-MS technique. Seventeen compounds including one oligosaccharide, two phenylpropanoids and fourteen flavonoid glycosides were determined by LC-MS combined with Shimadzu Composition Formula Predictor and database searching. The main fragmentation pathway of flavonoid glycosides was losing the saccharide groups in MSn analyses, such as glucose (-m/z 162), rhamnose (-m/z 146), glucuronic acid (-m/z 176), acetyl glucuronic acid (-m/z 218) and rutinose (-m/z 308). Retro-Diels-Alder reaction (RDA) scission was observed for some compounds which was useful for identifying the substituent groups on the flavonoid skeletons. It is suggested that LC-MS as an useful technique for quality analyzing in plant materials is fit for indentifying the flavonoid glycosides of R.officinalis.
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    • References (27)
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